Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours

被引:95
作者
Jia, Qin-Xiang [1 ]
Wang, Yan-Qin [1 ]
Yue, Qi [1 ]
Wang, Qing-Lun [2 ]
Gao, En-Qing [1 ]
机构
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1039/b811865e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two isomorphous Co-II and Mn-II three-dimensional coordination polymers with tetrazolate-5-carboxylate as magnetic mediator exhibit an unprecedented 3,4-connected self-penetrating net topology; a combination of canted antiferromagnetism and metamagnetism was observed in the Co-II compound, whereas the Mn-II compound shows typical antiferromagnetic behaviors.
引用
收藏
页码:4894 / 4896
页数:3
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