rel-(1R,6S,7S,8R,9S)-9-methyl-8-phenyl-6-[(1S,2R)-(2-phenylcyclohexyl)oxy]-4-aza-3,5-dioxatricyclo[5.2.1.0(4,9)]decane

被引：2

作者：

Dixon, JA

Swiss, KA

Denmark, SE

机构：

[1] Department of Chemistry, Roger Adams Laboratory, University of Illinois, Urbana, IL 61801

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196006671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, C26H31NO3, was determined by X-ray crystallography. It was found to be a unique bridged tricyclic nitroso acetal. Notable features include a chair conformation of the tetrahydro-1,2-oxazine ring and a highly pyramidalized N atom [Sigma(angles)=314.2(6)degrees]. The configurations of the five contiguous stereogenic centers in the nitroso acetal establish that the tandem cycloaddition sequence proceeded via an exo-[4+2]/endo-[3+2] pathway.

引用

页码：2561 / 2563

页数：3

共 9 条

[1] TANDEM INTER[4+2] INTRA[3+2] CYCLOADDITIONS .6. THE BRIDGED MODE [J].