An external chiral ligand controlled enantioselective opening of oxirane and oxetane by organolithiums

被引：73

作者：

Mizuno, M

Kanai, M

Iida, A

Tomioka, K

机构：

[1] KYOTO UNIV,GRAD SCH PHARMACEUT SCI,SAKYO KU,KYOTO 60601,JAPAN

[2] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

TETRAHEDRON | 1997年 / 53卷 / 31期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

D O I：

10.1016/S0040-4020(97)00701-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective nucleophilic opening reactions of cyclohexene oxide and 3-phenyloxetane were achieved by the combination of an external chiral ligand and organolithiums in the presence of boron trifluoride to give the corresponding alcohols in up to 47% ee. (C) 1997 Elsevier Science Ltd.

引用

页码：10699 / 10708

页数：10

共 27 条

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