New findings on CO electrooxidation at platinum nanoparticle surfaces

被引：61

作者：

Brimaud, S. ^{[1
]}

Pronier, S. ^{[2
]}

Coutanceau, C. ^{[1
]}

Leger, J. -M. ^{[1
]}

机构：

[1] Univ Poitiers, Catalyse Chim Organ Lab, Equipe Electrocatalyse, F-86022 Poitiers, France

[2] Univ Poitiers, Serv Mesure Phys, UMR CNRS 6503, F-86022 Poitiers, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 11期

关键词：

Oriented platinum nanoparticles; CO electrooxidation; Cyclic voltammetry;

D O I：

10.1016/j.elecom.2008.08.045

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Different unsupported platinum nanoparticles are synthesized via water-in-oil microemulsion and colloidal methods (PAA). TEM, adatom adsorption and cyclic voltammetry measurements give very coherent results concerning the surface structure of the crystallites. The combination of these results with CO stripping experiments leads us to assign the oxidation peak multiplicity to surface structure rather than to pure size effect. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1703 / 1707

页数：5

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