A new one-dimensional quaternary metal thiophosphate: Synthesis and structure of KNb2PS10

被引：52

作者：

Do, J ^{[1
]}

Yun, H ^{[1
]}

机构：

[1] AJOU UNIV,DEPT CHEM,SUWON 442749,SOUTH KOREA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 13期

关键词：

D O I：

10.1021/ic951644o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new one-dimensional quaternary metal thiophosphate KNb2PS10 has been synthesized by using a eutectic mixture of KCl/LiC1 and structurally characterized. The structure of KNb2PS10 is closely related to that of Nb2PS10 and comprises infinite one-dimensional chains composed of NbS8 and PS4 polyhedra. These chains are separated from one another by K+ cations. A chain may be formulated as (1)(infinity)[Nb24+P5+(S-2(2-))(3)(S2-)(4)(-)].

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页码：3729 / &

页数：3

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