Growth of tellurium clusters in presence of metal impurities

被引:1
作者
Herwig, C [1 ]
Becker, JA [1 ]
机构
[1] Univ Hannover, Inst Phys Chem & Elektrochem, D-30167 Hannover, Germany
关键词
PACS. 36.40.Jn Reactivity of clusters – 36.40.Qv Stability and fragmentation of clusters – 34.10.+x General theories and models of atomic and molecular collisions and interactions (including statistical theories, transition state, stochastic and trajectory models, etc.);
D O I
10.1007/s100530170058
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The growth of small tellurium clusters in helium and the influence of a metal impurity (dysprosium atoms) on the cluster size distribution are investigated in a double laser vaporization source. A model describing the role of the carrier gas as collision partner is presented, emphasizing the crucial influence of the gas pressure on cluster formation. Changes in cluster reactivity due to dysprosium addition are discussed in terms of ionic structures Dy3+(Te-N)(3-) containing a radical electron.
引用
收藏
页码:51 / 54
页数:4
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