Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groups

被引：37

作者：

Takeuchi, D ^{[1
]}

Osakada, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 227, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111697e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

pi-Allyl-nickel complexes initiated addition polymerisation of 2-phenyl-1-methylenecyclopropane to give a polymer with three-membered rings; the formed polymer showed a high T-g and negligible thermal decomposition up to 300 degreesC.

引用

页码：646 / 647

页数：2

共 22 条

[1]

BINGER P, 1977, LIEBIGS ANN CHEM, P1065

[2]

BINGER P, 1987, TOP CURR CHEM, V135, P77

[3]

Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO

[4]

2-3

[5]

DALLASTA G, 1962, MAKROMOLEKUL CHEM, V56, P224

[6] POLYMERIZATION OF CYCLOBUTENE RINGS .6. INFLUENCE OF ORGANOMETALLIC COMPOUND OF ZIEGLER-NATTA CATALYSTS ON MECHANISM OF POLYMERIZATION OF CYCLOBUTENE AND 3-METHYLCYCLOBUTENE [J].

DALLASTA, G .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (8PA1) :2397-&

[7] [eta(3)-methallyl-nickel-dad]PF6 complex: new catalyst precursor for ethylene polymerization [J].

deSouza, RF ;

Mauler, RS ;

Simon, LC ;

Nunes, FF ;

Vescia, DVS ;

Cavagnolli, A .

MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (09) :795-800

[8] COMPETITIVE CHAIN TRANSFER BY BETA-HYDROGEN AND BETA-METHYL ELIMINATION FOR THE MODEL ZIEGLER-NATTA OLEFIN POLYMERIZATION SYSTEM [ME2SI(ETA(5)-C5ME4)2]SC(CH2CH(CH3)2)(PME3) [J].

HAJELA, S ;

BERCAW, JE .

ORGANOMETALLICS, 1994, 13 (04) :1147-1154

[9] STEREOSPECIFIC POLYMERIZATION OF STYRENE GIVING THE SYNDIOTACTIC POLYMER [J].

ISHIHARA, N ;

KURAMOTO, M ;

UOI, M .

MACROMOLECULES, 1988, 21 (12) :3356-3360

[10] Late-metal catalysts for ethylene homo- and copolymerization [J].

Ittel, SD ;

Johnson, LK ;

Brookhart, M .

CHEMICAL REVIEWS, 2000, 100 (04) :1169-1203

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