Statistical properties of localized vibrational eigenstates

被引：51

作者：

Leitner, DM

Wolynes, PG

机构：

[1] Department of Chemistry, University of Illinois, Urbana

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 258卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(96)00614-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Statistical properties of localized eigenstates of a many-dimensional vibrational Hamiltonian are determined. In particular, the probability distribution of the inverse participation ratio is derived, which measures the degree of vibrational mixing. The distribution presented here is relevant to experimental and computational studies exploring vibrational mixing toward the onset of energy relaxation in molecules.

引用

页码：18 / 24

页数：7

共 20 条

[1]

ABOUCHACRA R, 1973, J PHYS C SOLID STATE, V6, P173

[2] STATISTICAL FLUCTUATIONS OF MATRIX-ELEMENTS IN REGULAR AND CHAOTIC SYSTEMS [J].