Terminal titanium(IV) (trimethylsilyl)imides prepared by oxidatively induced trimethylsilyl abstraction

被引：28

作者：

Bailey, Brad C.

Basuli, Falguni

Huffman, John C.

Mindiola, Daniel J. ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 11期

关键词：

D O I：

10.1021/om060168e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Titanium (trimethylsilyl)imide triflate complexes of the type (L)Ti=NSiMe3(OTf) (L- = [ArNC(CH3)](2)CH, Ar = 2,6- (Pr2C6H3)-Pr-i; L- = N[2-P(CHMe2)(2)-4-MeC6H3](2)) can be readily prepared by one- electron oxidation and subsequent trimethylsilyl abstraction in the Ti(III) precursors (L)TiCl-(N{SiMe3}(2)).

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页码：2725 / 2728

页数：4

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