Entropically driven self-assembly of multichannel rosette nanotubes

被引:121
作者
Fenniri, H [1 ]
Deng, BL
Ribbe, AE
Hallenga, K
Jacob, J
Thiyagarajan, P
机构
[1] Purdue Univ, Herbert C Brown Lab Chem 1393, W Lafayette, IN 47907 USA
[2] Argonne Natl Lab, Div Intense Pulsed Neutron Source, Argonne, IL 60439 USA
关键词
D O I
10.1073/pnas.032527099
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Rosette nanotubes are a new class of organic nanotubes obtained through the hierarchical self-assembly of low molecular weight synthetic modules in water. Here we demonstrate that these materials can serve as scaffolds for the supramolecular synthesis of multichannel nanotubular architectures and report on the discovery of their entropy-driven self-assembly process.
引用
收藏
页码:6487 / 6492
页数:6
相关论文
共 48 条
  • [1] [Anonymous], 1980, BIOPHYS CHEM
  • [2] Synthetic cyclic oligosaccharides - Syntheses and structural properties of a cyclo[(1->4)-alpha-L-rhamnopyranosyl-(1->4)-alpha-D-mannopyranosyl]trioside and -tetraoside
    Ashton, PR
    Brown, CL
    Menzer, S
    Nepogodiev, SA
    Stoddart, JF
    Williams, DJ
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (05) : 580 - 591
  • [3] Artificial molecular-level machines: Which energy to make them work?
    Ballardini, R
    Balzani, V
    Credi, A
    Gandolfi, MT
    Venturi, M
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) : 445 - 455
  • [4] Balzani V, 1998, COORDIN CHEM REV, V171, P3
  • [5] Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
  • [6] 2-X
  • [7] Biron E, 2000, BIOPOLYMERS, V55, P364, DOI 10.1002/1097-0282(2000)55:5<364::AID-BIP1010>3.0.CO
  • [8] 2-Z
  • [9] Bong DT, 2001, ANGEW CHEM INT EDIT, V40, P988, DOI 10.1002/1521-3773(20010316)40:6<988::AID-ANIE9880>3.0.CO
  • [10] 2-N