Study of new electrode materials based on sulfides with a spinel structure.

被引：8

作者：

Branci, Cyril ^{[1
]}

Sarradin, Joel ^{[1
]}

Olivier-Fourcade, Josette ^{[1
]}

Jumas, Jean-Claude ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Phys Chim Mat Condensee, UMR CNRS 5617, F-34095 Montpellier 5, France

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 311卷

关键词：

Rhodostannite; Insertion; Lithium; Titanium; Spinel; Electrode;

D O I：

10.1080/10587259808042368

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In this study, sulfide based spinel materials of tin and titanium were synthesised (Cu2FeTi3S8 and Cu2FeSn3S8). A topotactic substitution of tin by titanium atoms was performed in order to obtain electrode materials with high specific capacity associated to a good conductivity. According to the first electrochemical tests the Cu2FeTi3S8 spinel appears as a possible anodic material for the Rocking-Chair batteries.

引用

页码：69 / 74

页数：6

共 17 条

[1]

Armand M. B., 1980, Materials for Advanced Batteries. Proceedings of a NATO Symposium on Materials for Advanced Batteries, P145

[2] New tin-containing spinel sulfide electrodes for ambient temperature rocking chair cells [J].

Cochez, MA ;

Jumas, JC ;

Lavela, P ;

Morales, J ;

OlivierFourcade, J ;

Tirado, JL .

JOURNAL OF POWER SOURCES, 1996, 62 (01) :101-105

[3] LITHIATED RARE-EARTH THIOSPINELS AND SELENOSPINELS [J].

DELAMORA, P ;

GOODENOUGH, JB .

JOURNAL OF SOLID STATE CHEMISTRY, 1987, 70 (01) :121-128

[4] THE SULFOSPINEL-LITHIUM BATTERY SYSTEM - INITIAL STUDY OF 3 SULFOSPINELS [J].

EISENBERG, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (11) :2382-2383

[5] STRUCTURAL AND NMR-STUDY OF THE LITHIATED DEFECT THIOSPINELS LIXCU0.07[TI2]S4 (0-LESS-THAN X LESS-THAN-2) [J].

JAMES, ACWP ;

GOODENOUGH, JB ;

CLAYDEN, NJ .

JOURNAL OF SOLID STATE CHEMISTRY, 1988, 77 (02) :356-365

[6] Cathode materials for lithium rocking chair batteries [J].

Koksbang, R ;

Barker, J ;

Shi, H ;

Saidi, MY .

SOLID STATE IONICS, 1996, 84 (1-2) :1-21

[7] A LEAST SQUARE FIT PROGRAM [J].

KUNDIG, W .

NUCLEAR INSTRUMENTS & METHODS, 1969, 75 (02) :336-&

[8] Lithium intercalation and copper extraction in spinel sulfides of general formula Cu(2)MSn(3)S(8)(M=Mn, Fe, Co, Ni) [J].

Lavela, P ;

Tirado, JL ;

Morales, J ;

OlivierFourcade, J ;

Jumas, JC .

JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (01) :41-47

[9] ELECTROCHEMICAL LITHIUM INSERTION INTO IN16SN4S32 AND CU4IN20S32 SPINEL SULFIDES [J].

MORALES, J ;

TIRADO, JL ;

MOUBTASSIM, MLE ;

OLIVIERFOURCADE, J ;

JUMAS, JC .

JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 217 (02) :176-180

[10] TIME-DEPENDENT LITHIUM INSERTION IN MIXED-VALENCE TIN, INDIUM SULFIDE SPINELS - TIN MOSSBAUER-SPECTROSCOPY AND LITHIUM NMR [J].

MOUBTASSIM, MLE ;

OLIVIERFOURCADE, J ;

SENEGAS, J ;

JUMAS, JC .

MATERIALS RESEARCH BULLETIN, 1993, 28 (10) :1083-1092

← 1 2 →