One-step Beckmann rearrangement from carbonyl compounds and hydroxylamine hydrochloride in Al2O3/CH3SO3H (AMA) as a new reagent

被引：45

作者：

Sharghi, H ^{[1
]}

Sarvari, MH ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2001年 / 10期

关键词：

one-step Beckmann rearrangement; carbonyl compounds; hydroxylamine hydrochloride; Al2O3/CH3SO3H;

D O I：

10.3184/030823401103168424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and efficient synthetic procedure, for one-step Beckmann rearrangement of aldehydes and ketones with hydroxylamine hydrochloride and Al2O3/CH3SO3H (AMA) has been developed; cyclohexanone has been converted into e-caprolactam in a quantitative yield.

引用

页码：446 / 449

页数：4

共 27 条

[1] USE OF ZEOLITE CATALYSTS FOR EFFICIENT SYNTHESIS OF BENZOXAZOLES VIA BECKMANN REARRANGEMENT [J].