Chemical separation and ICP-AES determination of 22 metallic elements in U and Pu matrices using cyanex-923 extractant and studies on stripping of U and Pu

被引:55
作者
Argekar, AA [1 ]
Kulkarni, MJ [1 ]
Mathur, JN [1 ]
Page, AG [1 ]
机构
[1] Bhabha Atom Res Ctr, Div Radiochem, Trombay 400085, Mumbai, India
关键词
cyanex-923; uranium; plutonium; trace metals; ICP-AES; back-extraction;
D O I
10.1016/S0039-9140(01)00629-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Comprehensive studies have been carried out on the extraction behavior of uranium and plutonium matrices using cyanex-923 extractant. The near total extraction of U/Pu and quantitative separation of 22 metallic elements at trace levels has been established using inductively coupled plasma-atomic emission spectrometry (ICP-AES). The studies carried out on back extraction of U/Pu from organic phase have established the near total recovery of these matrices into the aqueous phase using 1 M Na2CO3 and saturated oxalic acid, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:591 / 601
页数:11
相关论文
共 20 条
[1]   RECOVERY AND PURIFICATION OF PLUTONIUM BY TRILAURYLAMINE EXTRACTION [J].
CHESNE, A ;
BATHELLIER, A ;
KOEHLY, G .
NUCLEAR SCIENCE AND ENGINEERING, 1963, 17 (04) :557-&
[2]  
CLEVELAND JM, 1970, CHEM PLUTONIUM, P192
[3]  
*COMM EN AT, 1973, 1174 COMM EN AT, P15
[4]  
CROUSE DJ, 1955, ORNL1959
[5]   Composition of CYANEX® 923, CYANEX® 925, CYANEX® 921 and TOPO [J].
Dziwinski, E ;
Szymanowski, J .
SOLVENT EXTRACTION AND ION EXCHANGE, 1998, 16 (06) :1515-1525
[6]   Determination of trace impurities in uranium, thorium and plutonium matrices by solvent extraction and inductively coupled plasma atomic emission spectrometry [J].
Gopalkrishnan, M ;
Radhakrishnan, K ;
Dhami, PS ;
Kulkarni, VT ;
Joshi, MV ;
Patwardhan, AB ;
Ramanujam, A ;
Mathur, JN .
TALANTA, 1997, 44 (02) :169-176
[7]   Chemical separation and inductively coupled plasma-atomic emission spectrometric determination of seventeen trace metals in thorium oxide matrix using a novel extractant - Cyanex-923 [J].
Kulkarni, MJ ;
Argekar, AA ;
Mathur, JN ;
Page, AG .
ANALYTICA CHIMICA ACTA, 1998, 370 (2-3) :163-171
[8]   INTER-ELEMENT INTERFERENCE STUDIES IN THE DETERMINATION OF TRACE AMOUNTS OF PLUTONIUM BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTROMETRY [J].
KULKARNI, MJ ;
THULASIDAS, SK ;
GOYAL, N ;
PAGE, AG ;
SASTRY, MD .
ANALYTICAL LETTERS, 1990, 23 (11) :2095-2106
[9]  
MENDEL JE, 1965, HW82103 USAEC
[10]   Use of a mixture of TRPO and TBP for the partitioning of actinides from high-level waste solutions of PUREX origin and its comparison with CMPO and other phosphorus-based extractants [J].
Murali, MS ;
Mathur, JN .
SOLVENT EXTRACTION AND ION EXCHANGE, 2001, 19 (01) :61-77