Modelling of ionic systems with a narrow acid base boundary

被引：27

作者：

Lindner, J ^{[1
]}

Snita, D ^{[1
]}

Marek, M ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Chem Engn, Ctr Nonlinear Dynam Chem & Biol Syst, CR-16628 Prague 6, Czech Republic

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2002年 / 4卷 / 08期

关键词：

D O I：

10.1039/b109525k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Formulation of a non-equilibrium model of an ionic system with a narrow acid base boundary (representing the electrolyte diode) is introduced and its predictions are compared with those based on the traditional simplified model with a local electroneutrality and instantaneous local dissociation equilibria assumptions. Significant differences have been found in the spatial profiles around the acid base boundary.

引用

页码：1348 / 1354

页数：7

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