Double pulse, calibration-free laser-induced breakdown spectroscopy: A new technique for in situ standard-less analysis of polluted soils

被引:107
作者
Corsi, Michela
Cristoforetti, Gabriele
Hidalgo, Montserrat
Legnaioli, Stefano
Palleschi, Vincenzo
Salvetti, Azenio
Tognoni, Elisabetta
Vallebona, Chiara
机构
[1] CNR, Appl Laser Spect Lab, Ist Proc Chimicofis, Area Ric Pisa, I-56124 Pisa, Italy
[2] Univ Alicante, Fac Ciencias Fase 2, Dept Quim Analit Nutr & Bromatol, Alicante 03080, Spain
关键词
D O I
10.1016/j.apgeochem.2006.02.004
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Laser-induced breakdown spectroscopy (LIBS) is a promising technique for in situ environmental analysis. The potential of this technique for accurate quantitative analysis could be greatly improved using an innovative experimental setup based on the use of two laser pulses suitably retarded - and analyzing the results with a standard-less procedure which overcomes the problems related to matrix effects. A new mobile instrument for soil analysis, developed at the Applied Laser Spectroscopy Laboratory in Pisa, is presented, and some experimental results are given. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:748 / 755
页数:8
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