Picoseconds time resolved photoinduced absorption by infrared active vibrations as a probe for charge photogeneration in MEH-PPV/C60 composites

被引:32
作者
Mizrahi, U [1 ]
Shtrichman, I
Gershoni, D
Ehrenfreund, E
Vardeny, ZV
机构
[1] Technion Israel Inst Technol, Dept Phys, IL-32000 Haifa, Israel
[2] Technion Israel Inst Technol, Inst Solid State, IL-32000 Haifa, Israel
[3] Univ Utah, Dept Phys, Salt Lake City, UT 84112 USA
关键词
picosecond time resolved IR spectroscopy; photoinduced absorption; PPV and derivatives;
D O I
10.1016/S0379-6779(98)00316-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have applied a visible pump mid-infrared probe picosecond time resolved technique, in order to study the photogeneration of charges in MEH-PPV/C-60 composites. The photoinduced infrared active vibrations on the polymer chains have been used as a direct measure for the photogenerated charges. We have found that, within our time resolution of similar or equal to 60 ps, polarons ate photogenerated on the MEH-PPV chains with a quantum yield of the order of 5%.
引用
收藏
页码:1182 / 1185
页数:4
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