Chloromethylthio-substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates

被引：2

作者：

Svistunova, IV ^{[1
]}

Shapkin, NP ^{[1
]}

Svistunov, GM ^{[1
]}

机构：

[1] Far Eastern State Univ, Vladivostok 690600, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 09期

关键词：

Aluminum; Spectroscopy; Chloride; Mass Spectroscopy; Chromium;

D O I：

10.1023/A:1013941600121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SCI-Substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates react with carbenes similarly to organylsulfenyl chlorides, with insertion of the carbenes into the S-Cl bond. Reaction with diazomethane gave chloromethylthio-substituted complexes whose structure was proved by IR, H-1 NMR, and mass spectroscopy. The thermal oxidative degradation of the complexes was studied. Chlorination of SCH3-substituted acetylacetonates does not yield such complexes.

引用

页码：1355 / 1357

页数：3