Palladium-catalyzed Reppe carbonylation

被引:481
作者
Kiss, G [1 ]
机构
[1] ExxonMobil Res & Engn Co, Corp Strateg Res, Annandale, NJ 08801 USA
关键词
D O I
10.1021/cr010328q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemistry, composition, performance and process applications of Pd Reppe-carbonylation catalysts were discussed. The reactivity and hydroesterification products of alkynes and conjugated and cumulated dienes were studied. The effect of nonligand promoters on activity and selectivity of Pd hydroesterification catalysts was examined. The side reactions in Pd-catalyzed hydroesterfication were also elaborated.
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页码:3435 / 3456
页数:22
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