Cumyl phenyldithioacetate and 1-phenylethyl phenyldithioacetate: Versatile ambient-temperature RAFT agents

被引：13

作者：

Barner-Kowollik, C ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2001年 / 54卷 / 05期

关键词：

D O I：

10.1071/CH01149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cumyl phenyldithioacetate (CPDA) and 1-phenylethyl phenyldithioacetate (1-PEPDA) as versatile ambient-temperature reversible addition fragmentation chain transfer (RAFT) agents were presented. The synthesis of both the compounds was proceeded by subsequent reaction of the resulting phenyldithioacetic acid with stryene and benzyl chloride with carbon disulphide. The compunds were found to have relatively poor radical stablizing ability and were well suited for controling styrene and 1-PEPDA polymerization at ambient temperature.

引用

页码：343 / 343

页数：1

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