Facile Shape Control of Co3O4 and the Effect of the Crystal Plane on Electrochemical Performance

被引:406
作者
Xiao, Xiaoling [1 ]
Liu, Xiangfeng [1 ]
Zhao, Hu [1 ]
Chen, Dongfeng [2 ]
Liu, Fengzhen [1 ]
Xiang, Junhui [3 ]
Hu, Zhongbo [1 ]
Li, Yadong [4 ]
机构
[1] Chinese Acad Sci, Grad Univ, Coll Mat Sci & Optoelect Technol, Beijing 100049, Peoples R China
[2] China Inst Atom Energy, Inst Nucl Phys, Beijing 102413, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
[4] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
基金
中国博士后科学基金;
关键词
Co3O4; crystal plane effect; electrochemical performance; electrodes; lithium ion batteries; LITHIUM-ION BATTERIES; REVERSIBLE CAPACITY; ELECTRODE MATERIALS; NANOWIRE ARRAYS; ANODE MATERIAL; GRAPHENE; NANOPARTICLES; NANOMATERIALS; CHALLENGES; NANOSHEETS;
D O I
10.1002/adma.201202271
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Co3O4 with three different crystal plane structures - cubes bounded by {001} planes, truncated octahedra enclosed by {111} and {001} planes, and octahedra with exposed {111} planes - is synthesized using a very simple one-step hydrothermal method. The three kinds of Co3O4 exhibit significantly different electrochemical performances and the effect of different exposed crystal planes on the electrochemical performance of Co3O4 is comprehensively studied.
引用
收藏
页码:5762 / 5766
页数:5
相关论文
共 40 条
  • [1] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [2] Synthesis, characterization, and li-electrochemical performance of highly porous Co3O4 powders
    Binotto, G.
    Larcher, D.
    Prakash, A. S.
    Urbina, R. Herrera
    Hegde, M. S.
    Tarascon, J-M.
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (12) : 3032 - 3040
  • [3] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [4] Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
    Cabana, Jordi
    Monconduit, Laure
    Larcher, Dominique
    Rosa Palacin, M.
    [J]. ADVANCED MATERIALS, 2010, 22 (35) : E170 - E192
  • [5] Self-Assembly and Embedding of Nanoparticles by In Situ Reduced Graphene for Preparation of a 3D Graphene/Nanoparticle Aerogel
    Chen, Wufeng
    Li, Sirong
    Chen, Chunhua
    Yan, Lifeng
    [J]. ADVANCED MATERIALS, 2011, 23 (47) : 5679 - +
  • [6] Functional Materials for Rechargeable Batteries
    Cheng, Fangyi
    Liang, Jing
    Tao, Zhanliang
    Chen, Jun
    [J]. ADVANCED MATERIALS, 2011, 23 (15) : 1695 - 1715
  • [7] High capacity anode materials for Li-ion batteries based on spinel metal oxides AMn2O4 (A = Co, Ni, and Zn)
    Courtel, Fabrice M.
    Duncan, Hugues
    Abu-Lebdeh, Yaser
    Davidson, Isobel J.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) : 10206 - 10218
  • [8] Atomic-scale investigation of defects, dopants, and lithium transport in the LiFePO4 olivine-type battery material
    Islam, MS
    Driscoll, DJ
    Fisher, CAJ
    Slater, PR
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (20) : 5085 - 5092
  • [9] A study on the charge-discharge mechanism of Co3O4 as an anode for the Li ion secondary battery
    Kang, YM
    Song, MS
    Kim, JH
    Kim, HS
    Park, MS
    Lee, JY
    Liu, HK
    Dou, SX
    [J]. ELECTROCHIMICA ACTA, 2005, 50 (18) : 3667 - 3673
  • [10] An organometallic approach for microporous organic network (MON)-Co3O4 composites: enhanced stability as anode materials for lithium ion batteries
    Lee, Han Sol
    Choi, Jaewon
    Jin, Jaewon
    Chun, Jiseul
    Lee, Sang Moon
    Kim, Hae Jin
    Son, Seung Uk
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (01) : 94 - 96