Silver(I) carboxylates: versatile inorganic analogs of carboxylic acids for supramolecular network formation

被引：65

作者：

Brammer, L ^{[1
]}

Burgard, MD ^{[1
]}

Rodger, CS ^{[1
]}

Swearingen, JK ^{[1
]}

Rath, NP ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 23期

关键词：

D O I：

10.1039/b108448h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimeric motifs formed by silver( I) carboxylates, illustrated here by the unit Ag-2(CF3CO2)(2), resemble the well known dimerization of carboxylic acids, i.e. 'H-2(RCO2)(2)', but exhibit greater flexibility, while permitting further elaboration into neutral coordination networks through linkage of the silver centres via ditopic ligands.

引用

页码：2468 / 2469

页数：2

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