High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis

被引：23

作者：

Castignolles, P ^{[1
]}

Gaborieau, M

Hilder, EF

Sprong, E

Ferguson, CJ

Gilbert, RG

机构：

[1] Univ Sydney, Key Ctr Polymer Colloids, Sch Chem F11, Sydney, NSW 2006, Australia

[2] Univ Tasmania, ACROSS, Sch Chem, Hobart, Tas 7001, Australia

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 01期

关键词：

acrylates (acrylic acid); capillary electrophoresis; molar mass distribution; oligomers; polyelectrolytes; separation techniques;

D O I：

10.1002/marc.200500641

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water-soluble monomers involved in emulsion polymerization processes.

引用

页码：42 / 46

页数：5

共 33 条

[1]

Adler M, 2004, E-POLYMERS

[2]

ANDREWS JR, 1999, POLYM HDB, P193

[3]

BUCHHOLZ FL, 2000, ULLMANNS ENCY IND CH, V21

[4] THE ROLE OF AQUEOUS-PHASE KINETICS IN EMULSION POLYMERIZATIONS [J].

CASEY, BS ;

MORRISON, BR ;

GILBERT, RG .

PROGRESS IN POLYMER SCIENCE, 1993, 18 (06) :1041-1096

[5]

CHARMOT D, 2004, Patent No. 2004089994

[6] DETERMINATION OF MOLECULAR-WEIGHT DISTRIBUTION OF SYNTHETIC FLEXIBLE-CHAIN POLY-ELECTROLYTES BY POLYACRYLAMIDE-GEL ELECTROPHORESIS [J].

CHEN, JL ;

MORAWETZ, H .

MACROMOLECULES, 1982, 15 (04) :1185-1188

[7]

Cölfen H, 2001, MACROMOL RAPID COMM, V22, P219, DOI 10.1002/1521-3927(20010201)22:4<219::AID-MARC219>3.0.CO

[8]

2-G

[9] Nonaqueous and aqueous capillary electrophoresis of synthetic polymers [J].

Cottet, H ;

Simó, C ;

Vayaboury, W ;

Cifuentes, A .

JOURNAL OF CHROMATOGRAPHY A, 2005, 1068 (01) :59-73

[10]

Cottet H, 2000, ELECTROPHORESIS, V21, P1493, DOI 10.1002/(SICI)1522-2683(20000501)21:8<1493::AID-ELPS1493>3.3.CO

← 1 2 3 4 →