Manipulation and Control of Molecular Beams

被引:279
作者
van de Meerakker, Sebastiaan Y. T. [2 ]
Bethlem, Hendrick L. [3 ]
Vanhaecke, Nicolas [4 ]
Meijer, Gerard [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany
[2] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands
[3] Vrije Univ Amsterdam, Inst Lasers Life & Biophoton, NL-1081 HV Amsterdam, Netherlands
[4] Univ Paris 11, Aime Cotton Lab, CNRS, F-91405 Orsay, France
基金
欧洲研究理事会;
关键词
BORN-OPPENHEIMER APPROXIMATION; BOSE-EINSTEIN CONDENSATION; ASYMMETRIC-TOP MOLECULES; DIPOLE-MOMENT; STORAGE-RING; STARK DECELERATION; MAGNETIC-FIELDS; SPECTROSCOPIC PARAMETERS; SUPERSONIC BEAMS; POLAR-MOLECULES;
D O I
10.1021/cr200349r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A study was conducted to demonstrate the manipulation of molecular beams with electric and magnetic fields. Seeded pulsed supersonic expansions were employed to conduct the investigations. The conservative forces exerted further downstream by the electric and magnetic fields enabled the researchers to manipulate and control the shape and the position of the distribution in the six-dimensional phase-space. All of the original experimental geometries were devised to create strong magnetic or electric field gradients to efficiently deflect particles from the beam axis. It was demonstrated that a detailed understanding of the influence of the external field on the energy level structure of the molecules was required for the manipulation of molecules with electric or magnetic fields.
引用
收藏
页码:4828 / 4878
页数:51
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