Diorganotellurium(IV) dihalides and secondary bonding: Revisiting the coordination polyhedra

被引：38

作者：

Zukerman-Schpector, J

Haiduc, I

机构：

[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil

[2] Univ Babes Bolyai, Fac Chim, RO-3400 Cluj Napoca, Romania

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 171卷

关键词：

coordination polyhedra; secondary bonds; organotellurium(IV) halides; lone pair;

D O I：

10.1080/10426500108046629

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination geometry of the central atom in diorganotellurium(IV) halides, almost invariably described as psi -trigonal bipyramidal, is in fact much more diversified. If intra and intermolecular secondary bonds and electron lone pairs are considered psi -trigonal bipyramidal, psi -octahedral, psi -pentagonal bipyramidal and some others coordination geometries can be identified. A careful reexamination of a number of published structures is presented, with the analysis of the coordination polyhedra.

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页码：73 / 112

页数：40

相关论文

共 53 条

[1] SYNTHESIS AND REACTIONS OF 1,6-BIS(2-BUTYLTELLUROPHENYL)-2,5-DIAZAHEXA-1,5-DIENE AND RELATED-COMPOUNDS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2-(BUTYLDICHLOROTELLURO)BENZALDEHYDE AND BIS[2-(HYDROXYIMINOMETHYL)PHENYL] DITELLURIDE [J].

ABID, KY ;

ALSALIM, NI ;

GREAVES, M ;

MCWHINNIE, WR ;

WEST, AA ;

HAMOR, TA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (09) :1697-1703

[2]

Alcock N. W., 1993, BONDING STRUCTURE ST, P195

[3]

Alcock N.W., 1972, ADV INORG CHEM, V15, P1, DOI DOI 10.1016/S0065-2792(08)60016-3

[4] SECONDARY BONDING .12. ARYLTELLURIUM IODIDES - CRYSTAL AND MOLECULAR-STRUCTURES OF CIS-PHENYLTELLURIUM(IV) AND TRANS-PHENYLTELLURIUM(IV) TRI-IODIDE AND 2 MODIFICATIONS OF DIPHENYLTELLURIUM(IV) DI-IODIDE [J].

ALCOCK, NW ;

HARRISON, WD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (05) :869-875

[5] SECONDARY BONDING .7. CRYSTAL AND MOLECULAR-STRUCTURES OF DIPHENYLTELLURIUM DICHLORIDE AND PHENYLTELLURIUM TRICHLORIDE [J].

ALCOCK, NW ;

HARRISON, WD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (02) :251-255

[6]

ALCOCK W, 1984, J CHEM SCO DA, P869

[7] THE X-RAY CRYSTAL-STRUCTURE OF BIS(PENTAFLUOROPHENYL)TELLURIUM DIFLUORIDE [J].

ARAMINI, J ;

BATCHELOR, RJ ;

JONES, CHW ;

EINSTEIN, FWB ;

SHARMA, RD .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (11) :2643-2648

[8] X-RAY CRYSTAL-STRUCTURES OF BIS(DICHLOROPHENYLTELLURO)METHANE AND BIS(TRICHLOROTELLURO)METHANE [J].

BATCHELOR, RJ ;

EINSTEIN, FWB ;

JONES, CHW ;

SHARMA, RD .

ORGANOMETALLICS, 1987, 6 (10) :2164-2168

[9] BONDING AND STRUCTURE OF DIPHENYLTELLURIUM(IV) DIFLUORIDE [J].

BERRY, FJ ;

EDWARDS, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11) :2306-2308

[10] STEREOSPECIFIC REACTIONS OF ARYL-TELLURIUM(IV) TRICHLORIDES WITH 3-CYCLOHEXENE-1-METHANOL AND 3-CYCLOHEXENE-1,1-DIMETHANOL - THE X-RAY CRYSTAL-STRUCTURE OF 2',4'-DIMETHOXYPHENYL(TRANS-6-OXABICYCLO[3.2.1]OCT-4-YL)TELLURIUM(IV) DICHLORIDE [J].

BORECKA, B ;

CAMERON, TS ;

MALIK, MA ;

SMITH, BC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1995, 73 (02) :255-263

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