Catalytic oxidation of cyclohexene with molecular oxygen by polyoxometalate-intercalated hydrotalcites

被引：20

作者：

Guo, J

Jiao, QZ

Shen, JP

Jiang, DZ

Yang, GH

Min, EZ

机构：

[1] EDUC INST JILIN PROV, DEPT CHEM, CHANGCHUN 130021, PEOPLES R CHINA

[2] RES INST PETR PROC, BEIJING 100083, PEOPLES R CHINA

来源：

CATALYSIS LETTERS | 1996年 / 40卷 / 1-2期

关键词：

oxidation; cyclohexene; polyoxometalate-intercalated hydrotalcite;

D O I：

10.1007/BF00807455

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cyclohexene was oxidized with molecular oxygen over transition-metal-substituted polyoxometalate-intercalated hydrotalcites to produce 2-cyclohexene-1-one and 2-cyclohexene-1-ol with high selectivity under mild reaction conditions.

引用

页码：43 / 45

页数：3

共 17 条

[1] A NOVEL METHOD IN PREPARATION OF PT/KL CATALYST FOR AROMATIZATION OF HEXANE [J].

DAI, LX ;

SAKASHITA, H ;

TATSUMI, T .

CHEMISTRY LETTERS, 1993, (02) :387-390

[2]

DREZDZON MA, 1990, ACS SYM SER, V437, P140

[3] SYNTHESIS OF ISOPOLYMETALATE-PILLARED HYDROTALCITE VIA ORGANIC-ANION-PILLARED PRECURSORS [J].

DREZDZON, MA .

INORGANIC CHEMISTRY, 1988, 27 (25) :4628-4632

[4]

GUO J, UNPUB CHEM RES CHIN

[5] SUSTAINED EPOXIDATION OF OLEFINS BY OXYGEN DONORS CATALYZED BY TRANSITION-METAL SUBSTITUTED POLYOXOMETALATES, OXIDATIVELY RESISTANT INORGANIC ANALOGS OF METALLOPORPHYRINS [J].

HILL, CL ;

BROWN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :536-538

[6] HOMOGENEOUS CATALYSTS BASED ON HETEROPOLY ACIDS (REVIEW) [J].

KOZHEVNIKOV, IV ;

MATVEEV, KI .

APPLIED CATALYSIS, 1983, 5 (02) :135-150

[7] SYNTHESIS AND PROPERTIES OF ANIONIC CLAYS PILLARED BY [XM12O40]N- KEGGIN IONS [J].

KWON, T ;

PINNAVAIA, TJ .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3) :23-33

[8] PILLARING OF LAYERED DOUBLE HYDROXIDES (LDHS) BY POLYOXOMETALATE ANIONS [J].

KWON, T ;

TSIGDINOS, GA ;

PINNAVAIA, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3653-3654

[9]

KWON T, 1989, CHEM MATER, V1, P490

[10] Pillaring of a Layered Double Hydroxide by Polyoxometalates with Keggin-Ion Structures [J].

Kwon, Taehyun ;

Pinnavaia, Thomas J. .

CHEMISTRY OF MATERIALS, 1989, 1 (04) :381-383

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