Bismetallocenes: Lanthanoid-transition-metal bonds through alkane elimination

被引：93

作者：

Butovskii, M. V. ^{[1
]}

Tok, O. L. ^{[1
]}

Wagner, F. R. ^{[2
]}

Kempe, Rhett ^{[1
]}

机构：

[1] Univ Bayreuth, Lehrstuhl Anorgan Chem 2, D-95440 Bayreuth, Germany

[2] Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 34期

关键词：

bismetallocenes; metal-metal bonds; rhenium; ytterbium; yttrium;

D O I：

10.1002/anie.200800407

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The reaction of monohydride complexes of the late transition metals with lanthanoid alkyl derivatives affords heterobimetallic compounds with direct metal-metal bonds. These covalent bonds are strongly polar and can be considered as donor-acceptor bonds. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6469 / 6472

页数：4

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