The ring-opening reaction of 3,3,3-trifluoropropene oxide with carbanions: Reaction of alpha-cyanocarbanions

被引：13

作者：

Katagiri, T ^{[1
]}

Akizuki, M ^{[1
]}

Kuriyama, T ^{[1
]}

Shinke, S ^{[1
]}

Uneyama, K ^{[1
]}

机构：

[1] OKAYAMA UNIV, FAC ENGN, DEPT APPL CHEM, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 06期

关键词：

D O I：

10.1246/cl.1997.549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nucleophilic ring-opening reaction of 3,3,3-trifluoropropene oxide (TFPO) was studied. Reaction of TFPO with carbanions stabilized by cyano group gave gamma-cyanohydrins in moderate to good yields. Meanwhile, reaction of the carbanions from malonic ester and nitromethane resulted in recovery of TFPO.

引用

页码：549 / 550

页数：2

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