Superior Stable Self-Healing SnP3 Anode for Sodium-Ion Batteries

被引:226
作者
Fan, Xiulin [1 ]
Mao, Jianfeng [1 ]
Zhu, Yujie [1 ]
Luo, Chao [1 ]
Suo, Liumin [1 ]
Gao, Tao [1 ]
Han, Fudong [1 ]
Liou, Sz-Chian [2 ]
Wang, Chunsheng [1 ]
机构
[1] Univ Maryland, Dept Chem & Biomol Engn, College Pk, MD 20742 USA
[2] Univ Maryland, Maryland Nanoctr, College Pk, MD 20742 USA
关键词
anode material; self-healing; SnP3; sodium-ion batteries; HIGH-PERFORMANCE ANODE; HIGH-CAPACITY; ENERGY-STORAGE; RATE CAPABILITY; NA-STORAGE; LOW-COST; ELECTRODES; PHOSPHORUS; CHALLENGES; INSERTION;
D O I
10.1002/aenm.201500174
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A SnP3 anode material with a theoretical volumetric capacity of 6890 mAh cm-3 is investigated for Na-ion batteries. The SnP3/C can deliver a reversible capacity of 810 mAh g-1 at a current density of 150 mA g-1 for 150 cycles. The superior performance is attributed to the strong bonding interaction of P and Sn after desodiation. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
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页数:7
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