Selective electrochemical dehalogenation of 2,4-dichlorophenoxyacetic acid in MeCN at room temperature

被引：13

作者：

Tsyganok, A

Otsuka, K

Yamanaka, I

Plekhanov, V

Kulikov, S

机构：

[1] TOKYO INST TECHNOL, DEPT CHEM ENGN, MEGURO KU, TOKYO 152, JAPAN

[2] INST CHEM NAT ORGAN MAT, KRASNOYARSK 660036, RUSSIA

来源：

CHEMISTRY LETTERS | 1996年 / 04期

关键词：

D O I：

10.1246/cl.1996.261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,4-Dichlorophenoxyacetic acid (commercial pesticide 2,4-D) can be dechlorinated by electrochemical reduction at different carbon materials under mild conditions to give phenoxyacetic acid with 80% selectivity at 75% conversion of 2,4-D (current efficiency 10 similar to 14%).

引用

页码：261 / 262

页数：2