The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions:: a new route to secondary amines

被引：16

作者：

Doctorovich, F ^{[1
]}

Trápani, C ^{[1
]}

机构：

[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, INQUIMAE, Dept Quim Inorgan Analit & Quim Fis, RA-1428 Buenos Aires, DF, Argentina

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 25期

关键词：

pentacyanonitrosylferrate; nitroprusside; diazotization; amine; complex; iron;

D O I：

10.1016/S0040-4039(99)00810-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：4635 / 4638

页数：4

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