Catalytic methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to dimethylhexane-1,6-dicarbamate using Bi(NO3)3

被引：53

作者：

Deleon, RG

Kobayashi, A

Yamauchi, T

Ooishi, J

Baba, T

Sasaki, M

Hiarata, F

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

[2] Takeda Chem Ind Ltd, Ibaraki 3140102, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 2002年 / 225卷 / 1-2期

关键词：

methoxycarbonylation; 1,6-hexanediamine; dimethyl carbonate; dimethylhexane-1,6-dicarbamate;

D O I：

10.1016/S0926-860X(01)00692-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Bi(NO3)(3), prepared by evacuating Bi(NO3)(2).5H(2)O at 353 K for 3 h, showed a high catalytic activity for the methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to form dimethylhexane-1,6-dicarbamate, the yield of which reached 84% at 353 K in 18 h. (C) 2002 Published by Elsevier Science B.V.

引用

页码：43 / 49

页数：7

共 11 条

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