Low temperature fabrication of hexagon shaped h-MoO3 nanorods and its phase transformation

被引：74

作者：

Dhage, S. R. ^{[1
]}

Hassan, M. S. ^{[1
]}

Yang, O. -Bong ^{[1
]}

机构：

[1] Chonbuk Natl Univ, Sch Semicond & Chem Engn, Jeonju 561756, Jeonbuk, South Korea

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2009年 / 114卷 / 2-3期

关键词：

Nanostructures; Chemical synthesis; Electron microscopy; Phase transitions; MOLYBDENUM TRIOXIDE; MOO3; MORPHOLOGY; OXIDE;

D O I：

10.1016/j.matchemphys.2008.10.076

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Hexagon shaped h-MoO3 nancrods have been fabricated via the probe sonication route using ammonium molybdate, urea and sodium dodecyl sulphate at 70 degrees C. Pure metastable h-MoO3 and alpha-MoO3 were obtained under the current synthetic conditions. The h-MoO3 phase was transformed to alpha-MoO3 phase at 400 degrees C, while the hexagon shape rods structures of h-MoO3 were collapsed and transformed to elongated particles of alpha-MoO3. As-prepared products were characterized by thermogravimetric analysis (TG), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HR-TEM). (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：511 / 514

页数：4

共 18 条

[1]

ANSERSSON G, 1950, ACTA CHEM SCAND, V4, P793

[2] INFLUENCE OF THE GRAIN MORPHOLOGY OF MOLYBDENUM TRIOXIDE ON ITS CATALYTIC PROPERTIES - OXIDATION OF METHANOL TO FORMALDEHYDE [J].

BAIKER, A ;

GASSER, D .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1986, 149 :119-124

[3] Controllable size, shape and morphology of molybdic acid self-aggregated with rhodamine B to construct functional material [J].

Guan, Zi Sheng ;

Zhang, Yu ;

Zhang, Qiang ;

Li, Dong Xu .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 302 (01) :113-122

[4] MoV-MoVI cationic ordering in the layered molybdate (C2H10N2)[Mo4O12] [J].

Guillou, N ;

Ferey, G ;

Whittingham, MS .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (10) :2277-2280

[5] METASTABLE HEXAGONAL MOLYBDATES - HYDROTHERMAL PREPARATION, STRUCTURE, AND REACTIVITY [J].

GUO, JD ;

ZAVALIJ, P ;

WHITTINGHAM, MS .

JOURNAL OF SOLID STATE CHEMISTRY, 1995, 117 (02) :323-332

[6]

Lou XW, 2002, CHEM MATER, V14, P4781, DOI 10.1021/cm0206237

[7] Preparation of hexagonal MoO3 by "Chimie Douce" reaction with NO2 [J].

Muraoka, Y ;

Grenier, JC ;

Petit, S ;

Pouchard, M .

SOLID STATE SCIENCES, 1999, 1 (2-3) :133-148

[8]

PARISE JB, 1991, J SOLID STATE CHEM, V117, P93

[9]

Patzke GR, 2002, ANGEW CHEM INT EDIT, V41, P2446, DOI 10.1002/1521-3773(20020715)41:14<2446::AID-ANIE2446>3.0.CO

[10]

2-K

← 1 2 →