Facile synthesis of tin oxide nanoparticles stabilized by dendritic polymers

被引:113
作者
Juttukonda, V [1 ]
Paddock, RL [1 ]
Raymond, JE [1 ]
Denomme, D [1 ]
Richardson, AE [1 ]
Slusher, LE [1 ]
Fahlman, BD [1 ]
机构
[1] Cent Michigan Univ, Dept Chem, Mt Pleasant, MI 48859 USA
关键词
D O I
10.1021/ja056902n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tin(IV) oxide nanoparticles were synthesized via the reaction of carbon dioxide with stannate ions immobilized by dendritic polymers. For PAMAM and PPI dendrimer hosts, resultant nanoparticle diameters were 2.5-3 nm; 3-3.5 nm nanoparticles resulted from use of a poly(ethyleneimine) hyperbranched polymer. Our conditions represent the only precedent for SnO2 nanoparticulate growth using dendritic architectures, as well as a novel application for CO2 as a reactive gas for the controlled growth of metal oxide nanoparticles. Copyright © 2006 American Chemical Society.
引用
收藏
页码:420 / 421
页数:2
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