Syntheses and ESR characterizations of conjugated polymers with nitrogen atoms

被引:13
作者
Goto, H
Iino, K
Akagi, K
Shirakawa, H
机构
[1] Univ of Tsukuba, Ibaraki, Japan
关键词
polyaniline and derivatives; electron spin resonance; solution processing;
D O I
10.1016/S0379-6779(97)80397-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present syntheses and properties of several kinds of polyaniline and polyaminopyridine derivatives. Polyaniline derivative with a stable radical group (PDDBO) and iodine-doped (doped-PmAPY) or oxidized polyaminopyridine (PmAPYO) showed one or two ''half-field'' ESR signals due to Delta m(s) = +/-2, in addition to a signal at central resonance field. For these polymers was strongly suggested a possibility of spin multiplet state including triplet one.
引用
收藏
页码:1683 / 1684
页数:2
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