共 2 条
Syntheses and ESR characterizations of conjugated polymers with nitrogen atoms
被引:13
作者:
Goto, H
Iino, K
Akagi, K
Shirakawa, H
机构:
[1] Univ of Tsukuba, Ibaraki, Japan
关键词:
polyaniline and derivatives;
electron spin resonance;
solution processing;
D O I:
10.1016/S0379-6779(97)80397-9
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
We present syntheses and properties of several kinds of polyaniline and polyaminopyridine derivatives. Polyaniline derivative with a stable radical group (PDDBO) and iodine-doped (doped-PmAPY) or oxidized polyaminopyridine (PmAPYO) showed one or two ''half-field'' ESR signals due to Delta m(s) = +/-2, in addition to a signal at central resonance field. For these polymers was strongly suggested a possibility of spin multiplet state including triplet one.
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页码:1683 / 1684
页数:2
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