Synthesis of pseudo-sugars based on desymmetrization of dienylsilanes.

被引：37

作者：

Angelaud, R ^{[1
]}

Landais, Y ^{[1
]}

机构：

[1] UNIV LAUSANNE, COLL PROPEDEUT, INST CHIM ORGAN, CH-1015 LAUSANNE, SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(97)10388-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthesis of pseudo-sugars using the desymmetrization of a dienylsilane, followed by a stereocontrolled introduction of the hydroxymethyl group at C5. is described. The CH2OH group at C5 was elaborated using either a regioselective cyclopropane-ring opening or a [2,3]-Wittig rearrangement. (C) 1997 Elsevier Science Ltd.

引用

页码：8841 / 8844

页数：4

共 27 条

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