Optical properties of thallium(I), lead(II) and bismuth(III) hexafluoroacetylacetonates. Intraligand phosphorescence under ambient conditions

被引：71

作者：

Strasser, A ^{[1
]}

Vogler, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

关键词：

thallium compounds; lead compounds; bismuth compounds; phosphorescence;

D O I：

10.1016/j.inoche.2003.12.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds TI(hfac), Pb(hfaC)(2) and Bi(hfac)(3) with hfac = hexafluoroacetylacetonate show a green phosphorescence (lambda(max) approximate to 500 nm) under ambient conditions. This emission which is facilitated by the heavy atom effect of the metals originates from the lowest-energy hfac intraligand triplet. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：528 / 530

页数：3

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