Physical and excess properties for binary mixtures of 1-methyl-3-octylimidazolium tetrafluoroborate, [Omim][BF4], ionic liquid with different alcohols

被引:111
作者
Arce, A [1 ]
Rodil, E [1 ]
Soto, A [1 ]
机构
[1] Univ Santiago Chile, Dept Chem Engn, E-15782 Santiago, Spain
关键词
density; refractive index; speeds of sound; dynamic viscosity; Omim][BF4; ionic liquid;
D O I
10.1007/s10953-006-8939-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, ionic liquids have increasingly gained importance as green solvents. The potential of these organic salts, which are moisture and air stable at room temperature, for new chemical processes and technologies is beginning to be recognized. Research on the thermophysical properties of ionic liquids and their mixtures form the basis for future applications. In this contribution, densities, refractive indices, speeds of sound and dynamic viscosities of 1-methyl-3-octylimidazolium tetrafluoroborate, [Omim][BF4], the room temperature ionic liquid (IL) in binary mixtures with methanol, ethanol, 1-propanol and 2-propanol were measured at 298.15K and atmospheric pressure. The excess molar volumes and molar refraction, isentropic compressibility and dynamic viscosity changes of mixing have been calculated and were satisfactorily correlated by the Redlich-Kister polynomial.
引用
收藏
页码:63 / 78
页数:16
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