A convenient synthesis of glycals employing in-situ generated Cp2TiCl

被引：20

作者：

Hansen, T ^{[1
]}

Krintel, SL ^{[1
]}

Daasbjerg, K ^{[1
]}

Skrydstrup, T ^{[1
]}

机构：

[1] Univ Aarhus, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(99)01266-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reductive elimination of acetylated glycosyl bromides to the corresponding glycal is easily achieved by mixing the bromide with Cp2TiCl2 and Mn in THF, and hence does not require the separate preparation of Cp2TiCl using glove-box techniques. (C) 1999 Elsevier Science Ltd. All rights reserved.

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收藏

页码：6087 / 6090

页数：4

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