Biogenetically important quinonemethides and other triterpenoid constituents of Salacia reticulata

被引:30
作者
Dhanabalasingham, B
Karunaratne, V
Tezuka, Y
Kikuchi, T
Gunatilaka, AAL
机构
[1] TOYAMA MED & PHARMACEUT UNIV,WAKAN YAKU RES INST,SUGITANI,TOYAMA 93001,JAPAN
[2] UNIV PERADENIYA,DEPT CHEM,PERADENIYA,SRI LANKA
关键词
Salacia reticulata var beta-diandra; Celastraceae; celastroloids; isoiguesterinol; 30-hydroxypristimerin; salacenonal; structural elucidation; biosynthesis;
D O I
10.1016/0031-9422(96)00886-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Phytochemical investigation of the outer root bark of Salacia reticulata var. beta-diandra (Celastraceae) has resulted in the isolation of two novel quinonemethide triterpenoids (celastroloids), isoiguesterinol and 30-hydroxypristimerin, along with salacenonal, several known celastroloids and friedo-oleanane triterpenoids. Details of the structural elucidation and H-1 and C-13 NMR spectral assignments of these compounds are presented and their biogenetic significance is discussed.
引用
收藏
页码:1377 / 1385
页数:9
相关论文
共 23 条
[1]  
BRUNING R, 1978, PHYTOCHEMISTRY, V17, P1821, DOI 10.1016/S0031-9422(00)88719-1
[2]  
CHANDRASENA JPC, 1935, CHEM PHARM CEYLON IN
[3]  
DELLEMONACHE F, 1979, J CHEM SOC P1, P3127
[4]  
DIAS MN, 1991, J CHEM RES M, P1801
[5]  
DIAS MN, 1991, J CHEM RES S, P238
[6]  
FERNANDO HC, 1989, TETRAHEDRON, V45, P5867
[7]  
GAMLATH CB, 1987, J CHEM SOC P1, P2457
[8]  
GONZALEZ AG, 1988, J CHEM RES-S, P20
[9]  
GONZALEZ AG, 1988, J CHEM RES M, P273
[10]   STUDIES ON TERPENOIDS AND STEROIDS .27. STRUCTURE OF A D-A-FRIEDO-OLEANANE TRITERPENOID FROM SALACIA-RETICULATA AND REVISION OF THE STRUCTURES OF KOKOONOL AND KOKZEYLANOL SERIES OF TRITERPENOIDS [J].
GUNATILAKA, AAL ;
DHANABALASINGHAM, B ;
KARUNARATNE, V ;
KIKUCHI, T ;
TEZUKA, Y .
TETRAHEDRON, 1993, 49 (45) :10397-10404