Some thermodynamic aspects of metal hydrogen systems

被引：31

作者：

Flanagan, TB ^{[1
]}

Oates, WA

机构：

[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA

[2] Univ Salford, Dept Mat, Salford M5 4WT, Lancs, England

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2005年 / 404卷

关键词：

thermodynamics; plateau sloping; hysteresis; calorimetry;

D O I：

10.1016/j.jallcom.2004.11.108

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The various degrees of equilibrium which are possible in the two-phase co-existence region of metal hydride systems will be reviewed. Some of these lead to invariant P-H2 and others to sloping plateaux. The effect of hysteresis on the thermodynamic properties of metal hydrides is discussed. Recent advances in theoretical first principle calculations of the energy of hydride formation are reviewed. (c) 2005 Elsevier B.V. All rights reserved.

引用

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页码：16 / 23

页数：8

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