Highly luminescent gels and mesogens based on elaborated borondipyrromethenes

被引:176
作者
Camerel, F
Bonardi, L
Schmutz, M
Ziessel, R
机构
[1] LCM, Associe CNRS, ULP ECPM, F-67087 Strasbourg, France
[2] CNRS, Inst Charles Sadron, UPR 22, F-67083 Strasbourg, France
关键词
D O I
10.1021/ja0606069
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular gels and liquid-crystalline materials containing borondipyrromethene (F-Bodipy) are a new class of highly luminescent materials built by attachment of long-chain alkoxydiacylamido scaffoldings to boradiazaindacene templates. Robust gels were formed in nonane, and luminescence spectroscopy was used to probe the aggregation processes of the flat indacene cores. Coincidently, columnar mesophase was obtained from the pure material over a wide temperature range, allowing textural observations by fluorescence microscopy. Copyright © 2006 American Chemical Society.
引用
收藏
页码:4548 / 4549
页数:2
相关论文
共 19 条
  • [1] Multistimuli, multiresponsive metallo-supramolecular polymers
    Beck, JB
    Rowan, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) : 13922 - 13923
  • [2] 3,5-diaryl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes:: Synthesis, spectroscopic, electrochemical, and structural properties
    Burghart, A
    Kim, HJ
    Welch, MB
    Thoresen, LH
    Reibenspies, J
    Burgess, K
    Bergstrom, F
    Johansson, LBÅ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (21) : 7813 - 7819
  • [3] A propeller-like uranyl metallomesogen
    Cardinaels, T
    Ramaekers, J
    Guillon, D
    Donnio, B
    Binnemans, K
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (50) : 17602 - 17603
  • [4] Aggregation of surfactant squaraine dyes in aqueous solution and microheterogeneous media: Correlation of aggregation behavior with molecular structure
    Chen, HJ
    Farahat, MS
    Law, KY
    Whitten, DG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (11) : 2584 - 2594
  • [5] Reversible optical transcription of supramolecular chirality into molecular chirality
    de Jong, JJD
    Lucas, LN
    Kellogg, RM
    van Esch, JH
    Feringa, BL
    [J]. SCIENCE, 2004, 304 (5668) : 278 - 281
  • [6] Water gelation by small organic molecules
    Estroff, LA
    Hamilton, AD
    [J]. CHEMICAL REVIEWS, 2004, 104 (03) : 1201 - 1217
  • [7] Kato T, 1998, ADV MATER, V10, P606, DOI 10.1002/(SICI)1521-4095(199805)10:8<606::AID-ADMA606>3.3.CO
  • [8] 2-K
  • [9] A coordination gelator that shows a reversible chromatic change and sol-gel phase-transition behavior upon oxidative/reductive stimuli
    Kawano, S
    Fujita, N
    Shinkai, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (28) : 8592 - 8593
  • [10] Quasi-solid-state dye-sensitized solar cells using room temperature molten salts and a low molecular weight gelator
    Kubo, W
    Kitamura, T
    Hanabusa, K
    Wada, Y
    Yanagida, S
    [J]. CHEMICAL COMMUNICATIONS, 2002, (04) : 374 - 375