Reversible cyclometallation at a ruthenium(II) centre

被引：42

作者：

Constable, EC

Dunne, SJ

Rees, DGF

Schmitt, CX

机构：

[1] Inst. für Anorganische Chemie, CH-4056 Basel

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metallated complex [Ru(tbp)(tpy)][PF6] [Htbp = 6-(2-thienyl)-2,2'-bipyridine, tpy = 2,2':6',2''-terpyridine] is converted to the non-metallated species [Ru(Htbp)(tpy)][PF6] containing an N,N,S-bonded Htbp ligand upon treatment with acid; this process is reversed upon reaction of [Ru(Htbp)(tpy)][PF6] with aqueous sodium hydroxide solution.

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页码：1169 / 1170

页数：2

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