Microflow photochemistry-a reactor comparison study using the photochemical synthesis of terebic acid as a model reaction

被引：30

作者：

Aida, Shin ^{[2
]}

Terao, Kimitada ^{[2
]}

Nishiyama, Yasuhiro ^{[2
]}

Kakiuchi, Kiyomi ^{[2
]}

Oelgemoeller, Michael ^{[1
]}

机构：

[1] James Cook Univ, Sch Pharm & Mol Sci, Ctr Biodiscovery & Mol Dev Therapeut BMDT, Townsville, Qld 4811, Australia

[2] Nara Inst Sci & Technol NAIST, Grad Sch Mat Sci, Nara 6300101, Japan

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 42期

关键词：

Photochemistry; Microflow; Terebic acid; Photoaddition; PHOTOSENSITIZED ADDITION; 2+2 PHOTOCYCLOADDITION; AQUEOUS-SOLUTION; MICROPHOTOCHEMISTRY; CARBOXYLATES; ISOPROPANOL; FURANONES; CHEMISTRY; SYSTEM;

D O I：

10.1016/j.tetlet.2012.07.143

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The continuous-microflow photochemical synthesis of terebic acid from maleic acid was investigated in two different microreactor set-ups. The results were subsequently compared to analogue experiments in a conventional chamber reactor. Based on conversion rates, reactor design and energy efficiency calculations, the simple microcapillary reactor showed the best overall performance. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：5578 / 5581

页数：4

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