Facile synthesis of enantiopure chiral molecular rectangles exhibiting induced circular dichroism

被引：32

作者：

Das, N

Ghosh, A

Singh, OM

Stang, PJ

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Univ Calcutta, Coll Sci, Dept Chem, Kolkata 700009, W Bengal, India

[3] Manipur Univ, Dept Chem, Imphal 795003, Manipur, India

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 08期

关键词：

D O I：

10.1021/ol060365+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The facile syntheses of enantiopure molecular rectangles using 1,8-bis(trans-Pt(PEt3)(2)(NO3))anthracene and optically pure D- or L-tartrate are reported in high yields. These self-assembled macrocycles are unique examples where the phenomenon of induced chiral dichroism (ICD) has been observed in chiral metallosupramolecular assemblies.

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页码：1701 / 1704

页数：4

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