Syntheses, characterizations and properties of boronoalkylalkoxycalix[4]arenes

被引：10

作者：

Lu, K ^{[1
]}

Wu, YJ ^{[1
]}

Wang, HX ^{[1
]}

Zhou, ZX ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

POLYHEDRON | 1999年 / 18卷 / 8-9期

基金：

中国国家自然科学基金;

关键词：

boronoalkylalkoxycalix[4]arene; synthesis; coordination; carbohydrates;

D O I：

10.1016/S0277-5387(98)00407-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some new calixarenes bearing boronic acid moieties, boronoalkylalkoxycalix[4]arenes, were synthesized by allylation, Claisen's rearrangement, alkylation, hydroboration and hydrolysis from 25,26,27,28-tetrahydroxycalixl[4] arene and their structures were identified by elemental analysis, IR, LH NMR, C-13 NMR, B-11 NMR, MS and UV spectra. The UV data showed that tetraalkcoxycalix[4]arene tetraalkyltriboronic acid could coordinate significantly with carbohydrates. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1153 / 1158

页数：6

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