Cryoscopic studies of the uranyl sulfate-water, uranyl nitrate-water, and uranyl nitrate-nitric acid-water systems

被引:6
作者
Apelblat, A [1 ]
机构
[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel
关键词
freezing points; uranyl sulfate solutions; uranyl nitrate-nitric acid solution; water activities; activity coefficients; osmotic coefficients;
D O I
10.1023/A:1021776213704
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Freezing point lowerings of aqueous solutions of uranyl sulfate in the concentration range m less than or equal to 0.40 mol-kg(-1) and the activity and osmotic coefficients, which were calculated using the Pitzer equations for 2:2 electrolytes, are presented. Crystallization temperatures are reported for 0 to 13 molar nitric acid and 10-150 g uranium per liter uranyl nitrate-nitric acid-water solutions.
引用
收藏
页码:769 / 776
页数:8
相关论文
共 21 条
[1]   CRYOSCOPY OF URANYL-NITRATE SOLUTIONS AND ACTIVITY-COEFFICIENTS [J].
APELBLAT, A .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (10) :1852-1854
[2]  
Apelblat A., 1973, J CHEM SOC F1, V69, P1618, DOI 10.1039/f19736901618
[3]  
BRUCE FR, 1958, PROGR NUCL ENERGY 3, V2
[4]  
COLANI A, 1926, B SOC CHIM FR, V39, P1243
[5]  
DITTRICK A, 1899, Z PHYS CHEM, V29, P449
[6]   PHASE EQUILIBRIUM STUDIES FOR TERNARY SYSTEM URANYL NITRATE - NITRIC ACID - WATER [J].
GAUNT, J ;
ADELMAN, M ;
BASTIEN, IJ .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (02) :527-&
[7]  
GUEMPEL O, 1929, B SOC CHEM BELG, V88, P443
[8]  
Hart R. G., 1958, PROGR NUCL ENERGY 3, V2, P544
[9]  
Pitzer KS., 1979, Act. Coeffic. Electrolyte Solutions, V1, P157
[10]  
ROBINSON RA, 1952, J CHEM SOC, P4543