High-resolution spectroscopy of aniline rare gas Van der Waals complexes: Results and comparison with theoretical predictions

被引：33

作者：

Becucci, M

Pietraperzia, G

Lakin, NM

Castellucci, E

Brechignac, P

机构：

[1] UNIV FLORENCE,DIPARTIMENTO CHIM,I-50121 FLORENCE,ITALY

[2] UNIV PARIS 11,PHOTOPHYS MOL LAB,CNRS,F-91405 ORSAY,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 260卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)00777-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-induced fluorescence spectra are presented for the first allowed electronic transitions in the near-UV of the aniline-argon and aniline-neon 1:1 Van der Waals complexes, formed in a molecular beam, The experimental linewidth was of the order of 10(-3) cm(-1) due to residual Doppler broadening and lifetime contributions, Single rotational eigenstates were resolved and complete sets of spectral assignments obtained using a rigid-rotor Hamiltonian model. From the rotational constants we extract both structural and dynamical information on the different clusters. This information is better understood in the light of a comparison with the results of quantum calculations.

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页码：87 / 94

页数：8

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