Characterization of internal order of colloidal crystals by optical diffraction

被引:21
作者
Allard, M [1 ]
Sargent, EH
Kumacheva, E
Kalinina, O
机构
[1] Univ Toronto, Dept Elect & Comp Engn, Toronto, ON M5S 3G4, Canada
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
colloid; optical diffraction; oscillatory shear; photonic crystal;
D O I
10.1023/A:1013397721552
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We report the results of the optical characterization of photonic crystals consisting of close-packed arrays of polymeric monodispersed microspheres. The excellent agreement of the diffraction peak wavelengths with Bragg's law enables a precise determination of the sphere diameter. Optical diffraction is used to assess the quality of the internal order of colloidal crystals and to identify optimum growth conditions. This work leads to an estimate of the average free propagation distance of light, which is limited by incoherent scattering due to lattice imperfections, of up to 30 lattice constants.
引用
收藏
页码:27 / 36
页数:10
相关论文
共 21 条
[1]   Photonic band gaps in 3D ordered fcc silica matrices [J].
Astratov, VN ;
Vlasov, YA ;
Karimov, OZ ;
Kaplyanskii, AA ;
Musikhin, YG ;
Bert, NA ;
Bogomolov, VN ;
Prokofiev, AV .
PHYSICS LETTERS A, 1996, 222 (05) :349-353
[2]  
Azaroff LV, 1968, ELEMENTS XRAY CRYSTA
[3]   Large-scale synthesis of a silicon photonic crystal with a complete three-dimensional bandgap near 1.5 micrometres [J].
Blanco, A ;
Chomski, E ;
Grabtchak, S ;
Ibisate, M ;
John, S ;
Leonard, SW ;
Lopez, C ;
Meseguer, F ;
Miguez, H ;
Mondia, JP ;
Ozin, GA ;
Toader, O ;
van Driel, HM .
NATURE, 2000, 405 (6785) :437-440
[4]   Photonic band gap formation in certain self-organizing systems [J].
Busch, K ;
John, S .
PHYSICAL REVIEW E, 1998, 58 (03) :3896-3908
[5]   A "core-shell" approach to producing 3D polymer nanocomposites [J].
Kalinina, O ;
Kumacheva, E .
MACROMOLECULES, 1999, 32 (12) :4122-4129
[6]   Enhanced backscattering from photonic crystals [J].
Koenderink, AF ;
Megens, M ;
van Soest, G ;
Vos, WL ;
Lagendijk, A .
PHYSICS LETTERS A, 2000, 268 (1-2) :104-111
[7]   Two-dimensional disordered photonic crystals with an average periodic lattice [J].
Li, HQ ;
Cheng, BY ;
Zhang, DZ .
PHYSICAL REVIEW B, 1997, 56 (17) :10734-10736
[8]   Fortuitously superimposed lattice plane secondary diffraction from crystalline colloidal arrays [J].
Liu, L ;
Li, PS ;
Asher, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2729-2732
[9]   Evidence of FCC crystallization of SiO2 nanospheres [J].
Miguez, H ;
Meseguer, F ;
Lopez, C ;
Mifsud, A ;
Moya, JS ;
Vazquez, L .
LANGMUIR, 1997, 13 (23) :6009-6011
[10]  
Miguez H, 1997, APPL PHYS LETT, V71, P1148, DOI 10.1063/1.119849