The first fullerene-metal sandwich complex:: An unusually strong electronic communication between two C60 cages

被引：66

作者：

Lee, K

Song, H

Kim, B

Park, JT ^{[1
]}

Park, S

Choi, MG

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea

[3] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[4] Yonsei Univ, Mol Struct Lab, Seoul 120749, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 12期

关键词：

D O I：

10.1021/ja017496k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Rh6(CO)9(dppm)2(μ3-η2,η2,η2-C60) (1) with C60 in refluxing chlorobenzene followed by treatment with CNR (R = CH2C6H5) at room temperature affords the first fullerene-metal sandwich complex Rh6(CO)5(dppm)2(CNR)(μ3-η2,η2,η2-C60)2 (2). Compound 2 has been characterized by an X-ray diffraction study. Electrochemical study of 2 reveals six well-separated reversible redox couples localized at C60 cages due to a strong electronic communication between the two C60 centers via the Rh6 cluster spacer. Copyright © 2002 American Chemical Society.

引用

页码：2872 / 2873

页数：2

共 29 条

[1] FULLERENE-ACETYLENE HYBRIDS - ON THE WAY TO SYNTHETIC MOLECULAR CARBON ALLOTROPES [J].