Core modified porphyrins - a macrocyclic platform for organometallic chemistry

被引：238

作者：

Chmielewski, PJ ^{[1
]}

Latos-Grazynski, L ^{[1
]}

机构：

[1] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 21-22期

关键词：

porphyrin; porphyrinoids; heteroporphyrins; organometallic chemistry;

D O I：

10.1016/j.ccr.2005.05.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An alteration of a metalloporphyrin coordination core, exemplified by 21-heteroporphyrins and 2-aza-21-carbaporphyrin (N-confused porphyrin, inverted porphyrin), provides a route of choice to stabilize unusual oxidation states and coordination geometries, affording a stabilization of such rare species as organometallic high-spin nickel(II) or copper(II) derivatives. This review focuses on reactivity and electronic structure of peculiar organometallic compounds trapped due to the appropriate choice of the suitable macrocyclic platform. (c) 2005 Elsevier B.V. All rights reserved.

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收藏

页码：2510 / 2533

页数：24

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